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Technical Paper

Zn-Ni Plating as a Cadmium Alternative

2007-09-17
2007-01-3837
In a 2-year program sponsored by SJAC, an aqueous electroplating process using alkaline Zn-Ni with trivalent chromium post treatment is under evaluation for high strength steel for aircraft application as an alternative to cadmium. Commercial Zn-15%Ni rack/barrel plating solutions are basis for plating aircraft parts or fasteners. Brightener was reduced from the original formula to form porous plating that enables bake-out of hydrogen to avoid hydrogen embrittlement condition. Properties of the deposit, such as appearance, adhesion, un-scribed corrosion resistance, and galvanic corrosion resistance in contact with Al alloy, were evaluated. Coefficient of friction was compared with Cd plating by torque-tension measurements. Evaluation of the plating for scribed corrosion resistance, primer adhesion, etc. will continue in FY2007.
Technical Paper

Zirconia Based Ceramic, In-Cylinder Coatings and Aftertreatment Oxidation Catalysts for Reduction of Emissions from Heavy Duty Diesel Engines

1997-02-24
970469
Diesel engines are coming under stricter requirements to reduce emissions. particularly those of particulates and nitrogen oxides (NOx). Recently, the U. S. EPA put into place staged requirements for heavy duty diesel engines in urban bus applications which are aimed at ultimately bringing pre-1994 engines into particulate emissions compliance with 1994 heavy duty on-road truck standards (0. 1 g/bhp-hr TPM). This reflects the need to control emissions in crowded urban environments. Zirconia based ceramic combustion management coatings, although originally developed for adiabatic or low heat rejection engines to boost thermal efficiency, have also been shown to contribute to the reduction in diesel emissions. Heavy duty transient testing of rebuilt 2-stroke MUI diesel bus engines equipped with stabilized zirconia based coatings applied by thermal spray process have shown significant reduction in exhaust opacity relative to a baseline, uncoated engine.
Technical Paper

Zinc-Air Batteries for Electric Vehicles

1991-09-01
911912
This paper describes a design for an electric vehicle (EV) battery system using a secondary (rechargeable) lead-acid section for power and a recyclable (mechanically replaced) primary zinc-air section for range. This approach optimizes the performance of each battery, resulting in a system with driving performance (acceleration, range, and refueling time) equal to that for internal combustion vehicles (ICVs). The physical characteristics of the system's components are highly compatible with their ICV counterparts, resulting in a substantial reduction in the cost of building prototype vehicles. The overall cost of the rechargeable/recyclable approach is estimated to be equal to that for the traditional single rechargeable battery approach.
Technical Paper

Zinc Distribution in Vacuum Brazed Alclad Brazing Sheet

1978-02-01
780301
Vacuum brazing technology is currently capable of producing aluminum automotive heat exchangers such as radiators and heater cores. The possible use of 7072 claddings on the surfaces exposed to the coolant to provide additional corrosion protection is of considerable interest. This paper describes the effect of typical vacuum brazing cycles on the distribution of zinc in 7072 clad vacuum brazing sheet. For heavier gauges (.05″), there is sufficient retained zinc in the post-braze composite. For lighter gauges (.02″ or less), nominal composition 7072 does not provide adequate retained zinc; however, if the initial zinc concentration is increased to 3% there is sufficient retained zinc so that the cladding is significantly more anodic than the core.
Standard

Zinc Die Casting Alloys

2017-12-20
CURRENT
J469_201712
Because of the drastic chilling involved in die casting and the fact that the solid solubilities of both aluminum and copper in zinc change with temperature, these alloys are subject to some aging changes, one of which is a dimensional change. Both of the alloys undergo a slight shrinkage after casting, which at room temperature is about two-thirds complete in five weeks. It is possible to accelerate this shrinkage by a stabilizing anneal, after which no further changes occur. The recommended stabilizing anneal is 3 to 6 h at 100 °C (212 °F), or 5 to 10 h at 85 °C (185 °F), or 10 to 20 h at 70 °C (158 °F). The time in each case is measured from the time at which the castings reach the annealing temperature. The parts may be air cooled after annealing. Such a treatment will cause a shrinkage (0.0004 in per in) of about two-thirds of the total, and the remaining shrinkage will occur at room temperature during the subsequent few weeks.
Technical Paper

Zinc Brazing of Automotive Aluminum Heat Exchangers

1993-03-01
930152
Provision of a layer of zinc on aluminium to provide the fillets for soldering is well established but this usually necessitates a thick layer of zinc (>30μm) and soldering at temperatures below 450°C. New technology has been developed to enable sound joints to be made on aluminium heat exchangers using a much thinner layer of zinc (4 to 8 μm typically) on the aluminium component to provide the joint. By the correct combination of flux and zinc coating thickness, joints have been obtained over a wide range of heating conditions. Preferred temperature cycles are similar to those used by the industry today for brazing of Aluminium:Silicon braze-clad aluminium components which should facilitate tranfer by industry to the new technology.
Technical Paper

Zero-dimensional Modeling of Flame Propagation During Combustion of Natural Gas/Hydrogen Mixtures

2023-04-11
2023-01-0190
To achieve global climate goals, greenhouse gas emissions must be drastically reduced. The energy and transportation sectors are responsible for about one third of the greenhouse gases emitted worldwide, and they often use internal combustion engines (ICE). One effective way to decarbonize ICEs may be to replace carbon-containing fossil fuels such as natural gas entirely, or at least partially, with hydrogen. Cost-effective development of sustainable combustion concepts for hydrogen and natural gas/hydrogen mixtures in ICEs requires the intensive use of fast and robust simulation tools for prediction. The key challenge is appropriate modeling of flame front propagation. This paper evaluates and applies different approaches to modeling laminar flame speeds from the literature. Both appropriate models and reaction kinetic calculations are considered.
Technical Paper

Zero-Waste PVD Cadmium for High Strength Steels

1998-11-11
983137
In spite of environmental issues related to cadmium and its electroplating process, electroplated cadmium is still extensively used in the aerospace and defense sectors. This trend is likely to continue especially for high strength steels because cadmium provides the best known corrosion and embrittlement protection for this application. Consequently, the environmental concerns related to the cadmium electroplating have been addressed using an alternative Zero-waste Physical Vapor Deposition (Z-PVD). This method does not use liquids, it recycles cadmium in situ, and is free of hydrogen embrittlement. The Z-PVD process is now in commercial production for the aerospace fasteners. The quality of the coatings has been at least equal to that of the electroplated cadmium.
Technical Paper

Zero-G Water Selection Separator: A Performance Tradeoff

1969-02-01
690642
This paper presents a trade-off study to select a water separator system for a 3-man, 140-day, zero-g mission. Included is a summary of feasible concepts, a compilation of data on existing hardware, and a comparison of the performance characteristics of each with respect to the overall system. Six approaches to zero-g water separation were considered and are discussed: hydrophobic/hydrophilic screens; integrated condenser-water separators; centrifugal separators; cellular sponges; vortex separators; and elbow separators. Some of these techniques have high-performance characteristics with regard to water removal efficiency. However, when reduced to hardware, these same techniques may not integrate well with the overall system. The system selected was the integrated condenser-water-separator. This system requires no power, has no moving parts, and has a very small envelope.
Technical Paper

Zero-Dimensional Spark Ignition Combustion Modeling - A Comparison of Different Approaches

2013-09-08
2013-24-0022
Internal combustion engines development with increased complexity due to CO2 reduction and emissions regulation, while reducing costs and duration of development projects, makes numerical simulation essential. 1D engine simulation software response for the gas exchange process is sufficiently accurate and quick. However, combustion simulation by Wiebe function is poorly predictive. The objective of this paper is to compare different approaches for 0D Spark Ignition (SI) modeling. Versions of Eddy Burn Up, Fractal and Flame Surface Density (FSD) models have been coded into GT-POWER platform, which connects thermodynamics, gas exchange and combustion sub-models. An initial flame kernel is imposed and then, the flame front propagates spherically in the combustion chamber. Flame surface is tabulated as a function of piston position and flame radius. The modeling of key features of SI combustion such as laminar flame speed and thickness and turbulence was common.
Technical Paper

Zero-Dimensional Heat Release Modeling Framework for Gasoline Compression-Ignition Engines with Multiple Injection Events

2019-09-09
2019-24-0083
A zero-dimensional heat release model was developed for compression ignition engines. This type of model can be utilized for parametric studies, off-line optimization to reduce experimental efforts as well as model-based control strategies. In this particular case, the combustion model, in a simpler form, will be used in future efforts to control the combustion in compression ignition engines operating on gasoline-like fuels. To allow for a realistic representation of the in-cylinder combustion process, a spray model has been employed to allow for the quantification of fuel distribution as well as turbulent kinetic energy within the injection spray. The combustion model framework is capable of reflecting premixed as well as mixing controlled combustion. Fuel is assigned to various combustion events based on the air-fuel mixture within the spray.
Technical Paper

Zero-Delay Light-Off - A New Cold-Start Concept with a Latent Heat Storage Integrated into a Catalyst Substrate

2007-04-16
2007-01-1074
This study aims at a new concept for a fast catalyst light-off in combining a latent heat storage with a catalyst. The arrangement of a latent heat storage device into the exhaust system offers significant benefits for the catalyst light-off. Different arrangements have been examined. The first arrangement, called the sequential arrangement, comprises a latent heat storage device and a subsequent catalyst. This offers a significantly faster heat up of the catalyst compared to the standard arrangement. By that emissions during the cold start phase can be significantly reduced. The setup of the latent heat storage device is designed for a high heat transfer between storage material and the exhaust gas. A second integrated arrangement of a latent heat storage and a catalyst into one common substrate has also been set up and investigated. The main advantage of this arrangement is that the catalyst itself is kept on its operation temperature during the engine off time.
Technical Paper

Zero Gravity Phase Separator Technologies - Past, Present and Future

1992-07-01
921160
Spacecraft life support equipment is often challenged with two phase flow, where liquid and gas exist together. In the zero gravity environment of an orbiting spacecraft, the behavior of a liquid/gas interface is dominated by forces not usually observed in one “G” due to the overwhelming effects of gravity. The normal perceptions no longer apply. Water does not run down hill and bubbles do not rise to the surface. Surface energy, capillary forces, wetting characteristics and momentum effects predominate. Techniques and equipment have been developed to separate the liquid/gas mixture into its constituent parts with various levels of efficiency and power consumption.
Technical Paper

Zero Dimensional Models for EGR Mass-Rate and EGR Unbalance Estimation in Diesel Engines

2017-09-04
2017-24-0070
A precise estimation of the recirculated exhaust gas rate and oxygen concentration as well as a predictive evaluation of the possible EGR unbalance among cylinders are of paramount importance, especially if non-conventional combustion modes, which require high EGR flow-rates, are implemented. In the present paper, starting from the equation related to convergent nozzles, the EGR mass flow-rate is modeled considering the pressure and the temperature upstream of the EGR control valve, as well as the pressure downstream of it. The restricted flow-area at the valve-seat passage and the discharge coefficient are carefully assessed as functions of the valve lift. Other models were fitted using parameters describing the engine working conditions as inputs, following a semi-physical and a purely statistical approach. The resulting models are then applied to estimate EGR rates to both conventional and non-conventional combustion conditions.
Journal Article

Zero Dimension Heat Release Modeling for Gasoline, Ethanol, Isobutanol and Diisobutylene Operating in Compression Ignition with Varying Injection Strategies

2023-04-11
2023-01-0188
Gasoline compression ignition shows great potential in reducing NOx and soot emissions with competitive thermal efficiency by leveraging the properties of gasoline fuels and the high compression ratio of compression ignition engines operating air-dilute. Meanwhile, its control becomes challenging due to not only the properties of different gasoline-type fuels but also the impacts of injection strategies on the in-cylinder reactivity. As such, a computationally efficient zero-dimension combustion model can significantly reduce the cost of control development. In this study, a previously developed zero-dimension combustion model for gasoline compression ignition was extended to multiple gasoline-type fuel blends and a port fuel injection/direct fuel injection strategy. Tests were conducted on a 12.4-liter heavy-duty engine with five fuel blends.
Technical Paper

Zero Carbon Emission Aviation Fuel Technology Review - The Hydrogen Pathway

2024-01-08
2023-36-0029
The commercial aviation currently accounts for roughly 2.5 % of the global CO2 emissions and around 3.5% of world warming emissions, taking into account non CO2 effects on the climate. Its has grown faster in recent decades than the other transport modes (road, rail or shipping), with an average rate of 2.3%/year from 1990 to 2019, prior to the pandemic. Moreover, its share of Greenhouse (GHG) emissions is supposed to grow, with the increasing demand scenario of air trips worldwide. This scenario might threaten the decarbonization targets assumed by the aviation industry, in line with the world efforts to minimize the climate effects caused by the carbon emissions. In this context, hydrogen is set as a promising alternative to the traditional jet fuel, due to its zero carbon emissions.
Standard

ZINC DIE CASTING ALLOYS

1989-01-01
HISTORICAL
J469_198901
Because of the drastic chilling involved in die casting and the fact that the solid solubilities of both aluminum and copper in zinc change with temperature, these alloys are subject to some aging changes, one of which is a dimensional change. Both of the alloys undergo a slight shrinkage after casting, which at room temperature is about two-thirds complete in five weeks. It is possible to accelerate this shrinkage by a stabilizing anneal, after which no further changes occur. The recommended stabilizing anneal is 3 to 6 h at 100 °C (212 °F), or 5 to 10 h at 85 °C (185 °F), or 10 to 20 h at 70 °C (158 °F). The time in each case is measured from the time at which the castings reach the annealing temperature. The parts may be air cooled after annealing. Such a treatment will cause a shrinkage (0.0004 in per in) of about two-thirds of the total, and the remaining shrinkage will occur at room temperature during the subsequent few weeks.
Technical Paper

ZERO-ODP REFRIGERANTS FOR LOW TONNAGE CENTRIFUGAL CHILLER SYSTEMS

1996-05-01
961320
This paper investigates the use of several zero-ozone depleting potential (zero-ODP) HFC refrigerants, including HFC-134a, HFC-227ca, HFC-227ea, HFC-236ea, HFC-236cb, HFC-236fa, HFC-245cb, and HFC-254cb, for centrifugal chiller applications. We took into account the thermodynamic properties of the refrigerant and aerodynamic characteristics of the impeller compression process in this evaluation.. For a given operating temperature lift, there are significant differences in the pressure ratio required by each refrigerant and this variation in pressure ratio directly affects compressor size, efficiency, and performance. A comparison of the HFC refrigerant candidates with CFC-114 shows that HFC-236ea, HFC-227ca and HFC-227ea are viable alternatives for centrifugal water chillers. HFC-236ea has properties closest to CFC-114, and will result in comparible performance, but will require a slightly larger impeller and a purge system.
Technical Paper

ZENITH: A Nano-Satellite for Atmospheric Monitoring

2015-09-15
2015-01-2395
This paper describes the ZENITH Nano-Satellite cum planetary atmospheric entry vehicle, called CanSat, the first Nano-Satellite project that has been developed by Delhi Technological University (Formerly Delhi College of Engineering), India. The satellite will function for monitoring the concentrations of various gases in the atmosphere. For this, the satellite consists of arduino microcontroller interfaced with the various Micro-electromechanical system (MEMS) gas sensors for measuring the concentrations of various gases such as carbon dioxide, carbon monoxide, methane, nitrous oxides, ozone, etc. The data obtained from the CanSat will be transmitted to the ground station where all the data will be stored and also the locations will be stored using GPS sensor. The academic goal of this project is to recruit students to the field of space science and technology.
Technical Paper

Z-type Schlieren Setup and its Application to High-Speed Imaging of Gasoline Sprays

2011-08-30
2011-01-1981
Schlieren and shadowgraph imaging have been used for many years to identify refractive index gradients in various applications. For evaporating fuel sprays, these techniques can differentiate the boundary between spray regions and background ambient gases. Valuable information such as the penetration rate, spreading angle, spray structure, and spray pattern can be obtained using schlieren diagnostics. In this study, we present details of a z-type schlieren system setup and its application to port-fuel-injection gasoline sprays. The schlieren high-speed movies were used to obtain time histories of the spray penetration and spreading angle. Later, these global parameters were compared to specifications provided by the injector manufacturer. Also, diagnostic parameters such as the proportion of light cut-off at the focal point and the orientation of knife-edge (schlieren-stop) used to achieve the cut-off were examined.
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